History of Radiocarbon-14 Dating The method developed in the 1940's and was a ground-breaking piece of research that would change dating methods forever. A team of researchers led by Willard F. Libby calculated the rate of radioactive decay of the 14 C isotope (4) in carbon black powder. As a test, the team took samples of acacia wood from two Egyptian Pharaohs and dated them; the results came ...